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align="center" style="font-size:medium;text-align:center;"> <span style="font-size:14pt;font-family:宋體;">污泥熱解氣化技術(shù)</span><span style="font-size:14pt;"></span> </p> <p class="MsoNormal" align="left" style="font-size:medium;"> <span style="font-size:14pt;font-family:宋體;">污泥熱解氣化技術(shù)是華天環(huán)保污泥全流程處理技術(shù)的核心技術(shù)之一。</span><span style="font-size:14pt;"></span> </p> <p class="MsoListParagraph" style="font-size:medium;margin-left:36pt;text-indent:-36pt;"> <span style="font-size:14pt;">一、<span style="font-size:7pt;line-height:normal;font-family:""> </span></span><span style="font-size:14pt;font-family:宋體;">什么是熱解氣化？</span><span style="font-size:14pt;"></span> </p> <p class="MsoNormal" style="font-size:medium;text-indent:28pt;"> <span style="font-size:14pt;font-family:宋體;">熱解氣化焚燒是一種傳統的工業(yè)化生產(chǎn)技術(shù)，廣泛應用于煤炭、石化等行業(yè)。</span><span style="font-size:14pt;"><span></span></span> </p> <p class="MsoNormal" style="font-size:medium;text-indent:27pt;"> <span style="font-size:14pt;font-family:宋體;">概念：熱</span><span style="font-size:14pt;"> </span><span style="font-size:14pt;font-family:宋體;">解</span><span style="font-size:14pt;"> pyrolysis</span><span style="font-size:14pt;font-family:宋體;">：</span><span style="font-size:14pt;"> </span><span style="font-size:14pt;font-family:宋體;">有機物在無(wú)氧或貧氧的環(huán)境下加熱，使之轉化為氣態(tài)、液態(tài)、固態(tài)的可燃物質(zhì)的化學(xué)反應過(guò)程。</span><span style="font-size:14pt;"></span> </p> <p class="MsoNormal" style="font-size:medium;text-indent:27pt;"> <span style="font-size:14pt;font-family:宋體;">反應原理</span><span style="font-size:14pt;"> </span><span style="font-size:14pt;font-family:宋體;">：有機固體廢棄物</span><span style="font-size:14pt;">+</span><span style="font-size:14pt;font-family:宋體;">熱量，在無(wú)氧</span><span style="font-size:14pt;">/</span><span style="font-size:14pt;font-family:宋體;">貧氧狀態(tài)下，生成可燃氣</span><span style="font-size:14pt;">+</span><span style="font-size:14pt;font-family:宋體;">爐渣。</span><span style="font-size:14pt;"></span> </p> <p class="MsoListParagraph" style="font-size:medium;margin-left:36pt;text-indent:-36pt;"> <span style="font-size:14pt;">二、<span style="font-size:7pt;line-height:normal;font-family:""> </span></span><span style="font-size:14pt;font-family:宋體;">污泥氣化過(guò)程</span><span style="font-size:14pt;"></span> </p> <p class="MsoNormal" style="font-size:medium;text-indent:35pt;"> <span style="font-size:14pt;font-family:宋體;">污泥氣化技術(shù)是利用有機質(zhì)在高溫貧氧條件下裂解的性質(zhì)，將污泥烘干后投入密閉蓄熱氣化爐內，經(jīng)過(guò)<span>900-1100℃</span>的高溫貧氧氣化環(huán)境，使污泥中的有機成分裂解揮發(fā)，轉化為以一氧化碳、氫氣、烷類(lèi)氣體為主的可燃氣體，污泥中的無(wú)機物以殘渣形式排出。如圖<span>1</span></span> </p> <img src="/static/uploads/attached/image/20210317/20210317165457_95045.jpg" alt="" /> <p> <br /> </p> <p class="MsoNormal" style="font-size:medium;text-indent:35pt;"> 圖1 </p> <p class="MsoNormal" style="text-indent:35pt;"> <span>1.干燥：污泥進(jìn)入氣化爐，在下降的過(guò)程中與高溫熱解燃氣接觸，污泥中的水變成蒸汽和熱解燃氣一起排出爐外，污泥逐步變干燥。</span> </p> <p class="MsoNormal" style="text-indent:35pt;"> <span>2.干餾：干燥后的污泥，在200-500℃的貧氧條件下干餾，生成烷類(lèi)（CmHn）、一氧化碳（CO）、焦油等可燃氣體和水蒸氣（H2O），從爐體上端排氣口排出。</span> </p> <p class="MsoNormal" style="text-indent:35pt;"> <span>3.氣化：經(jīng)過(guò)碳化后的污泥，主要殘留物是焦炭和無(wú)機不可燃物，在600-1000℃高溫下，與燃燒產(chǎn)生的CO2反應生成CO，部分碳化物通過(guò)水蒸氣的作用，發(fā)生氧化還原反應生成CO、H2等可燃氣體，從爐體下段排氣口排出。</span> </p> <p class="MsoNormal" style="text-indent:35pt;"> <span>4.燃燒：污泥氣化反應完成后，剩余固定炭在800-1100℃高溫下，與氧氣反應生成CO2,為整個(gè)氣化反應過(guò)程提供熱量。</span> </p> <p class="MsoNormal" style="text-indent:35pt;"> <span>三、<span> </span>污泥氣化工藝流程</span> </p> <div> <img src="/static/uploads/attached/image/20210317/20210317165850_63116.jpg" alt="" /><br /> </div> <p class="MsoNormal" style="text-align:center;font-size:medium;text-indent:28pt;"> 圖2 </p> <p class="MsoNormal" style="text-align:left;text-indent:28pt;"> <span><span>四、</span><span> </span><span>技術(shù)優(yōu)勢</span></span> </p> <p class="MsoNormal" style="text-indent:28pt;"> <span>1.遏制二噁英：從原理上遏制了二噁英類(lèi)物質(zhì)的生成。尾氣排放中二噁英濃度遠低于國家標準的0.1ng/m3 。污泥氣化后可燃氣燃燒尾氣二噁英濃度為0.045ng/m3。 </span> </p> <p class="MsoNormal" style="text-indent:28pt;"> <span>2. 無(wú)飛灰產(chǎn)生：成型氣化、流速低、料層高 </span> </p> <p class="MsoNormal" style="text-indent:28pt;"> <span> 3. 固化重金屬：高溫燃燒，包裹固化重金屬 </span> </p> <p class="MsoNormal" style="text-indent:28pt;"> <span> 4. 減量化明顯：以含水率80%計，減量化高達90%以上 </span> </p> <p class="MsoNormal" style="text-indent:28pt;"> <span> 5. 無(wú)害化徹底：處理溫度高達1100℃ </span> </p> <p class="MsoNormal" style="text-indent:28pt;"> <span> 6. 資源化利用：污泥自身有機質(zhì)能源被有效利用 </span> </p> <p class="MsoNormal" style="text-indent:28pt;"> <span>對比發(fā)現：尾氣排放中二噁英濃度遠低于國家標準的0.1ng/m3 </span> </p> <p class="MsoNormal" style="text-indent:28pt;"> <span>污泥焚燒尾氣二噁英濃度約0.3ng/m3，而污泥氣化后可燃氣燃燒尾氣二噁英濃度為0.045ng/m3，遠遠低于國家標準。</span> </p> <p class="MsoNormal" style="text-indent:28pt;"> <span>五、遏制二噁英的原理 </span> </p> <p class="MsoNormal" style="text-indent:28pt;"> <span> 二噁英的分子結構是由1或2個(gè)氧原子聯(lián)結2個(gè)被氯原子取代的苯環(huán)，氧、氯以及苯環(huán)是二噁英生成的基本條件。污泥熱解氣化過(guò)程中，燃燒段以上完全處于貧氧狀態(tài)，沒(méi)有氧原子參與反應，故不會(huì )產(chǎn)生二噁英；污泥到達燃燒段時(shí)，有機物全部干餾，僅剩炭在燃燒，沒(méi)有含氯苯環(huán)產(chǎn)生，所以從避免了二噁英類(lèi)物質(zhì)生成的條件。</span> </p> <p class="MsoNormal" style="text-indent:28pt;"> <span><img src="/static/uploads/attached/image/20210317/20210317170012_96245.jpg" alt="" /><br /> </span> </p> <div> <br /> </div> <p class="MsoNormal" style="text-align:center;font-size:medium;text-indent:21pt;"> <span style="font-size:16px;font-family:宋體;">二噁英的分子結構</span><span style="font-size:16px;">（圖3）</span> </p> <p class="MsoNormal" style="text-align:center;font-size:medium;text-indent:21pt;"> <span style="font-size:16px;"> </span> </p> <p class="MsoNormal" align="center" style="font-size:medium;text-align:center;"> <span style="font-size:14pt;font-family:宋體;">二噁英檢測報告</span><span style="font-size:14pt;"></span> </p> <p class="MsoNormal" align="center" style="text-align:left;font-size:medium;"> <span style="font-size:14pt;font-family:宋體;"><img src="/static/uploads/attached/image/20210317/20210317170301_86006.jpg" alt="" /><br /> </span> </p> <p class="MsoNormal" align="center" style="text-align:left;font-size:medium;"> <span style="font-size:14pt;font-family:宋體;"><img src="/static/uploads/attached/image/20210317/20210317170324_12436.jpg" alt="" /><br /> </span> </p> <p class="MsoNormal" align="center" style="text-align:left;font-size:medium;"> <span style="font-size:14pt;font-family:宋體;"> </span> </p> <p class="MsoNormal" style="font-size:medium;"> <b><span style="font-size:14pt;font-family:宋體;">六、無(wú)飛灰產(chǎn)生的原理</span></b><b><span style="font-size:14pt;"></span></b><span style="font-size:14pt;"></span> </p> <p class="MsoNormal" style="font-size:medium;"> <span style="font-size:14pt;font-family:宋體;">飛灰屬于危險廢物，隨尾氣排放，造成煙塵污染，使煙氣處理難度增加；同時(shí)也是二噁英類(lèi)有毒物質(zhì)及重金屬附著(zhù)和傳播的載體。</span><span style="font-size:14pt;"><span></span></span> </p> <p class="MsoNormal" style="font-size:medium;"> <span style="font-size:14pt;font-family:宋體;">氣化焚燒無(wú)飛灰產(chǎn)生的原因</span><span style="font-size:14pt;">:</span> </p> <p class="MsoNormal" style="font-size:medium;"> <span style="font-size:14pt;">1.</span><span style="font-size:14pt;font-family:宋體;">污泥在進(jìn)入氣化設備前已被成型；</span><span style="font-size:14pt;"><span></span></span> </p> <p class="MsoNormal" style="font-size:medium;"> <span style="font-size:14pt;">2.</span><span style="font-size:14pt;font-family:宋體;">污泥在設備內部處于相對靜止狀態(tài)；</span><span style="font-size:14pt;"><span></span></span> </p> <p class="MsoNormal" style="font-size:medium;"> <span style="font-size:14pt;">3.</span><span style="font-size:14pt;font-family:宋體;">氣化爐內氣流速度極低，灰不易帶出；</span><span style="font-size:14pt;"><span></span></span> </p> <p class="MsoNormal" style="font-size:medium;"> <span style="font-size:14pt;">4.</span><span style="font-size:14pt;font-family:宋體;">設備內有</span><span style="font-size:14pt;">4-5</span><span style="font-size:14pt;font-family:宋體;">米的料層厚度，渣層在設備最底部，料層起到很好的過(guò)濾作用，灰渣不易帶出。</span><span style="font-size:14pt;"><span></span></span> </p> <img src="/static/uploads/attached/image/20210317/20210317170430_67719.jpg" alt="" /><br /> <p> <br /> </p> <div style="text-align:left;"> <span></span><span></span> </div> <p> <br /> </p> <p class="MsoNormal" align="left" style="font-size:medium;text-indent:28pt;"> <span style="font-size:14pt;"> </span> </p> <p class="MsoNormal" style="font-size:medium;"> <span style="font-size:14pt;font-family:宋體;">七、固化重金屬的原理</span><span style="font-size:14pt;"></span> </p> <p class="MsoNormal" style="font-size:medium;text-indent:35pt;"> <span style="font-size:14pt;font-family:宋體;">在高溫狀態(tài)下，污泥中所含的重金屬成分變成氧化物牢牢地包裹固化，避免了重金屬在自然環(huán)境中浸出，殘渣中的重金屬離子被包裹或被氧化，不再產(chǎn)生毒性。將殘渣用于建筑材料，制作水泥、免燒磚，或作為路基材料利用。</span><span style="font-size:14pt;"></span> </p> <img src="/static/uploads/attached/image/20210317/20210317170538_22494.jpg" alt="" /> <p> <br /> </p> <p class="MsoNormal" align="left" style="font-size:medium;text-indent:28pt;"> <span style="font-size:14pt;"> </span> </p> <p class="MsoNormal" align="center" style="font-size:medium;text-align:center;text-indent:30pt;"> <span style="font-size:12pt;font-family:宋體;">高溫熔融殘渣</span><span style="font-size:12pt;"></span> </p> <img src="/static/uploads/attached/image/20210317/20210317170720_33576.jpg" alt="" /><img src="/static/uploads/attached/image/20210317/20210317170733_68340.jpg" alt="" /><br /> <p> <br /> </p> <p class="MsoNormal" align="center" style="text-align:left;font-size:medium;text-indent:28pt;"> <span style="font-size:12pt;font-family:宋體;">殘渣制作的免燒磚 </span><span style="font-size:12pt;font-family:宋體;">殘渣制作的加汽塊</span> </p> <p class="MsoNormal" align="center" style="text-align:left;text-indent:28pt;"> <span></span><span><span>氣化殘渣重金屬檢測遠低于國家標準（見(jiàn)檢驗報告）</span></span> </p> <p class="MsoNormal" align="center" style="text-align:left;"> 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